If $n>1$ is an integer, then $\sum \limits_{k=1}^n \frac1k$ is not an integer.
If you know Bertrand's Postulate, then you know there must be a prime $p$ between $n/2$ and $n$, so $\frac 1p$ appears in the sum, but $\frac{1}{2p}$ does not. Aside from $\frac 1p$, every other term $\frac 1k$ has $k$ divisible only by primes smaller than $p$. We can combine all those terms to get $\sum_{k=1}^n\frac 1k = \frac 1p + \frac ab$, where $b$ is not divisible by $p$. If this were an integer, then (multiplying by $b$) $\frac bp +a$ would also be an integer, which it isn't since $b$ isn't divisible by $p$.
Does anybody know an elementary proof of this which doesn't rely on Bertrand's Postulate? For a while, I was convinced I'd seen one, but now I'm starting to suspect whatever argument I saw was wrong.